Department of Chemistry
@ University of Albertahttp://www.chem.ualberta.ca/http://www.chem.ualberta.ca/shapeimage_1_link_0shapeimage_1_link_1
 
 

Complexes containing two or more adjacent metal centres offer an added chemical dimension over those containing a single metal; not only can the metals act independently but they can also act in a cooperative manner leading to chemistry that differs appreciably from that displayed by the single metal counterparts. 

It is the prospect of metal cooperativity which is of primary interest to my research group, in its application to organic synthesis and catalysis.  We are therefore involved in the design, synthesis and characterization of novel complexes containing two or more adjacent metal centres and with the subsequent chemistry of these species.

until the 2010 CSC Conference and Exhibition in Torontohttp://www.csc2010.ca/
Ir/M (M = Ru, Os) Chemistry
Ir_M_%28M_%3D_Ru,_Os%29_Chemistry.html
C–F Activation of Fluoroolefins
CF_Activation_of_Fluoroolefins.html
Hemilabile P/N Ligands
Hemilabile_P_N_Ligands.html
Bridging Silanes
Bridging_Silanes.html
NHCs in Rh/Os Systems
NHCs_in_Rh_Os_Systems_1.html

Di–NHC–Bridged Species