Chem 161 - Lecture Outline & Assignment #3
Readings
Problems
Outline
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Readings:
TWG Solomons and CB Fryhle "Organic Chemistry" 8th Edition (2004):
- Functional Group List on pp 70-71 and Periodic Table (1 page back from Back Cover)
- Chapter 7 – Alkenes and Alkynes I: Properties and Synthesis
- Chapter 8 – Alkenes and Alkynes II: Addition Reactions
- Chapter 11 – Alcohols and Ethers: Sections 11.1 to 11.5, especially 11.4
- Chapter 10 – Radical Reactions: re-read especially Sections 10.9 and 10.10
- Special Topic A – Chain Growth Polymers
Problems:
Do Not turn in, answers available in "Study Guide and Solutions Manual for Organic Chemistry" by Solomons and Fryhle.
Chapter 7:
7.1 (E/Z only); 7.2; 7.3; 7.5 to 7.9; 7.13; 7.15; 7.16 to 7.19; 7.21; 7.22; 7.28; 7.32; 7.37; 7.38
Chapter 8:
8.1; 8.2; 8.4; 8.5; 8.7 to 8.9; 8.11; 8.13; 8.16; 8.21; 8.23; 8.27; 8.28; 8.29; 8.34; 8.37; 8.38; 8.39; 8.42; 8.43
Chapter 10:
10.2
Chapter 11:
11.4
Special Topic A:
A1; A4
Lecture Outline 3:
Alkenes and Alkynes – Addition and Elimination Reactions
- Structure and Nomenclature
- Alkenes with one double bond
- Nomenclature
- Orbital Hybridization
- Stereoisomerism - cis, trans, and Z, E.
- Cycloalkenes
- Polyenes
- Alkynes
- Nomenclature
- Structure and Orbital Hybridization
- Physical Properties and Sources
- Physical Properties - solubility, density, BP, MP
- Occurrence of Alkenes and Alkynes
- Terpenes and Isoprene Units
- Reactions of Multiple Bonds between Carbons
- General Characteristics - Addition Reactions, electrophiles and nucleophiles
- Arrow Conventions for Mechanisms
- Addition Reactions of Alkenes - Stereospecificity
- Hydrogenation
- Halogenation
- Halohydrin Formation
- Hydrogen Halide Addition – Markovnikov’s Rule
- Water Addition - Alcohol synthesis
- Alcohol Addition - Ether synthesis
- Mercuration - Demercuration
- Hydroboration - Oxidation
- Hydroboration and Treatment with Acid
- Oxidation of Alkenes
- Ozonolysis
- Osmium Tetroxide and Potassium Permanganate
- Epoxidation
- Addition Reactions of Alkynes
- Hydrogenation
- Halogenation
- Hydrogen Halide Addition
- Hydration - aldehyde and ketone synthesis - tautomers
- Markovnikov Addition of Water
- Hydroboration - Oxidation
- Oxidation of Alkynes
- Ozonolysis
- Potassium Permanganate
- Synthesis of Alkenes and Alkynes - Eliminations
- Elimination Reactions
- El Mechanism - Saytzeff Rule, Leaving Groups
- E2 Mechanism - Stereochemistry
- Synthesis of Alkenes and Alkynes
- Dehydrohalogenation
- Dehalogenation of vic - dihalides
- Dehydration of alcohols
- Hydrogenation - Dehydrogenation
- Replacement of Acetylenic Hydrogen
- Acidity of Alkynes
- Alkylation - Substitution Reactions
- Coupling of Acetylenes
- Polymerization and Radical Reactions of Alkenes
- Radical Additions
- Hydrogen Halide Addition
- Addition of Alkyl Radicals
- Polymers and Polymerization
- Polyethylene and General Mechanism
- Other types of Polymers - Nomenclature and Properties
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