Chem 263 - Lecture Outline & Assignment #5
Readings
Problems
Outline
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Readings:
TWG Solomons and CB Fryhle "Organic Chemistry" 8th Edition (2004):
- Functional Group List on pp 70-71 and (Periodic Table) one page back from Inside Back Cover
- Relative Strength of Acids and Bases on Inside Front Cover - same table page 105
- Chapter 20 – Amines
- Special Topic E – Alkaloids
- Chapter 24– Amino Acids and Proteins – Read for general background
Problems:
Do Not turn in, answers available in "Study Guide and Solutions Manual for Organic Chemistry " by Marc Loudon and Joseph Stowell. This is available in the Bookstore or can be borrowed from Cameron Library's Reserve Reading Room.
Chapter 20:
20.1 to 20.8; 20.11; 20.15; 20.16; 20.21; 20.46; 20.48
Special Topic E:
E1; E2; E3
Lecture Outline 5: Amines, Alkaloids & Introduction to Amino Acids
- Structure and Nomenclature of Amines
- Nomenclature
- Common names - heterocyclic amines
- Systematic (IUPAC)
- Basicity of Amines and Physical Properties
- Preparation of Amines
- Nucleophilic Substitution Reactions (SN2) on Alkyl Halides and Sulfonates
- Reduction of Nitro Compounds
- Reductive Amination of Imines Derived from Ketones and Other Amines
- Reduction of Alkyl Cyanides (Nitriles) or Amides
- Hofmann Degradation of Amides
- Gabriel Synthesis
- Reactions of Amines
- Acid-Base Reactions
- Alkylation
- Acylation (Ammonolysis of Carboxylic Acid Derivatives to Form Amides)
- Reaction with Nitrous Acid
- Aliphatic Amines
- Aromatic Amines - Reactions of Diazonium Salts
- Replacement reactions
- Coupling reactions
- Some Alkaloids in Nature and Their Importance
- General Structure and Properties of Amino Acids and Peptides
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