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complete publications list
(red
denotes undergraduate researcher,
blue
denotes graduate or post-doctoral researcher)
116. "Synthesis of tri- and tetraynes using a butadiynyl
synthon," K. Azyat, E. Jahnke, T. Rankin,
R.R. Tykwinski, ChemComm, in press.
115. "Synthesis of Extended Polyynes: Toward Carbyne,"
W.A. Chalifoux, R.R. Tykwinski,
Compt. Rend. Chim., in press (pci081462, part of the special issue:
Modern Acetylene Chemistry).
114. "Synthesis of Soluble Oligo- and Polymeric Pentacene-Based
Materials," D.
Lehnherr,
R. McDonald, R.R. Tywkinski, Tetrahedron 2008, 64, 1144911461
(part of the Symposium in Print: Carbon-Rich Nanostructures).
113. "Synthesis of Conjugated Pentacene Dimers: Materials
Toward Photoconductive Gain," D.
Lehnherr,
J.
Gao,
F. A. Hegmann, R. R. Tykwinski, Org. Lett. 2008, 10, 47794782.
112. "Chiral cis-Platinum Acetylide Complexes via Diphosphine
Ligand Exchange: Effect of the Ligand," A.L.
Sadowy, M.J. Ferguson, R. McDonald, R.R. Tykwinski, Organometallics
2008, 27, 63216325.
111. "Exploring Electronically Polarized Pentacenes,
" D.
Lehnherr,
R. McDonald, R.R. Tykwinski, Org. Lett. 2008, 10, 41634166.
110. "Dynamic Properties of Solid Ammonium Cyanate,"
A. Desmedt, S. J. Kitchin, K. D. M. Harris, F. Guillaume, R. R. Tykwinski,
M. Xu, M. A. Gonzalez, J. Phys. Chem. C 2008, 112, 1587015879.
109. "Synthesis and Solid-State Structure of Perfluorophenyl
End-Capped Polyynes," J. Kendall,
R. McDonald, M.J. Ferguson, R.R. Tykwinski, Org. Lett. 2008, 11, 21632166.
108.
"Synthesis and Characterization of Cyclic Alkyl Tetraynes,"
A. Spantulescu, T. Luu, Y. Zhao,
R. McDonald, R. R. Tykwinski, Org. Lett. 2008, 10,
609-612.
107. Expanded Radialenes: Modular Synthesis and Properties
of Cross-Conjugated Enyne Macrocycles, R. R. Tykwinski, M.
Gholami, S. Eisler, Y. Zhao, F. Melin, L. Echegoyen, Pure
Appl. Chem. 2008, 80, 621-637.
106. A One-Pot Formation and Derivatization of Di- and
Triynes Based on the Fritsch-Buttenberg-Wiechell Rearrangement,
T. Luu, Y. Morisaki, N. Cunningham,
R. R. Tykwinski, J. Org. Chem. 2007, 72, 9622-9629.
105. Pentacene Oligomers and Polymers: Functionalization
of Pentacene to Afford Mono-, Di-, Tri- and Polymeric Materials,
D. Lehnherr, R. R. Tywkinski,
Org. Lett. 2007, 9, 4583-4586.
104. Synthesis and Characterization of a New Generation
of Expanded Radialenes, Bis-radialenes, and Radiaannulenes,
M. Gholami, F. Melin, R. McDonald,
M. J. Ferguson, L. Echegoyen, R. R. Tykwinski, Angew. Chem. Int.
Ed. 2007, 46, 90819085.
103. "One-pot Synthesis and Functionalization of Polyynes
via Alkylidene Carbenoids, T. Luu,
Y. Morisaki, R. R. Tykwinski, Synthesis 2008, 1158-1162
(invited PSP paper).
102. "Donor/Acceptor Effects on Linear and Nonlinear Optical
Properties of Geminal-Diethynylethenes (g-DEEs),"
Y. Zhao, N. Zhou, A.D. Slepkov,
S.C. Ciulei, R. McDonald, F.A. Hegmann, R.R. Tykwinski, Helv.
Chim. Acta 2007, 90, 909-927.
101.
"Tris(4-biphenyl)silyl endcapped polyynes,"
W.A. Chalifoux, M.J. Ferguson, R.R. Tykwinski, Eur. J.
Org. Chem. 2007, 1001-1006.
100.
"Regioselective Trapping of Terminal Polyynes with Benzyl Azide,"
T. Luu, R. McDonald, R.R. Tykwinski,
Org. Lett. 2006, 8, 6035-6038.
99.
"Synthesis and Stability a Homologous Series Triynol Natural
Products and Their Analogues," T. Luu,
R. R. Tykwinski, J. Org. Chem. 2006,
71, 8982-898.
98.
"Preparation and Reductive Decomposition of 2-Iodoxybenzenesulfonic
Acid; X-Ray Crystal Structure of 1H-1-Hydroxy-1,2,3-benziodoxathiole
3,3-dioxide," A.Y. Koposov, D.N. Litvinov,
V.V. Zhdankin, R. McDonald, R.R. Tykwinski, Eur. J. Org. Chem.
2006, 4791-4795.
97.
"Two-Photon Absorption in 2-D Conjugated Quadrupolar Chromophores,"
A.D. Slepkov, F.A. Hegmann, R.R. Tykwinski,,
K Kamada, Koji Ohta, J.A. Marsden, E.L. Spitler, J.J. Miller, M.M.
Haley, Opt. Lett. 2006, 31, 3315-3317.
96.
"Chiral, Cross-conjugated iso-Polydiacetylenes,"
C.A. Lewis,R.R. Tykwinski, ChemComm 2006,
3625-3627.
95.
"Anisotropy of transient photoconductivity in functionalized
pentacene single crystals,” O. Ostroverkhova,
D. G. Cooke, F. A. Hegmann R. R. Tykwinski S. R. Parkin, J.
E. Anthony, Appl. Phys. Lett. 2006 89, 192113.
94.
"Oligomeric and Polymeric Systems with a Cross-conjugated p-Framework,"
M. Gholami, R.R Tykwinski, Chem. Rev.
2006, 106, 4997-5027.
93. "Polyyne Synthesis via Carbene/Carbenoid
Rearrangements," W.A. Chalifoux, R.R. Tykwinski,
Chem. Rec.2006, 6, 169-182.
92. "A One-pot Synthesis and Functionalization
of Polyynes," Y. Morisaki, T. Luu, R.R.
Tykwinski, Org. Lett. 2006, 8, 689-692.
91. "Porphyrinic Assemblies of Pyridine-containing
Macrocycles," K. Campbell, R. McDonald,
R. R. Tykwinski, J. Porphyrins Phthalocyanine 2005,
9, 794-802.
90. "Reductive Bergman-Type Cyclizations of
Cross-Conjugated Enediynes to Fulvene and Fulvalene Anions: The Role
of Charge Distribution," N. Treitel, L. Eshdat, T. Sheradsky,
P.M. Donovan, R.R. Tykwinski, L.T. Scott, H. Hopf, M. Rabinovitz,
J. Am. Chem. Soc. 2006, 128, 4703-4709.
89.
"A Divergent Synthesis of Triyne Natural Products and Glycosylated
Analogues Using a Carbenoid Rearrangement," T.
Luu, W. Shi, T.L. Lowary, R.R. Tykwinski,
Synthesis 2005, 3167-3178 (invited feature article).
88.
Review: "Synthesis of Naturally Occurring Polyynes," A.L.K.
Shi Shun, R.R. Tykwinski, Angew. Chem. Int. Ed. 2006,
45, 10341057.
87.
"Hyperpolarized 129Xe NMR Spectroscopic Investigation of Porous
Organic Macrocycles," K.J.
Ooms, K. Campbell, R.R. Tykwinski,
R.E. Wasylishen, J. Mater. Chem. 2005, 15, 43184327.
86.
"Optical and transient photoconductive properties of pentacene
and functionalized pentacene thin films: Dependence on film morphology,"
O. Ostroverkhova, S. Shcherbyna, D.G.
Cooke, R.F. Egerton, F.A. Hegmann, R.R. Tykwinski, S.R.
Parkin, J.E. Anthony, J. Appl. Phys. 2005, 98,
033701.
85.
"Esters of 2-Iodoxybenzoic Acid (IBX-Esters): Hypervalent Iodine
Oxidizing Reagents with a Pseudobenziodoxole Structure," V.V.
Zhdankin, A.Y. Koposov, D.N. Litvinov M.J. Ferguson, R. McDonald,
T. Luu, R.R. Tykwinski, J. Org. Chem.
2005, 70, 6484-6491.
84.
"Synthesis and Characterization of Cross-conjugated Oligo(phenylene
enynylene)s," J. Cho,
Y. Zhao, R.R. Tykwinski, ARKIVOC 2005, Part (iv),
142-150 (invited contribution special issue honoring Professor Nikolia
Zefirov).
83.
"Characterization of Porosity In Organic and MetalOrganic
Macrocycles by Hyperpolarized 129Xe NMR Spectroscopy," K.
Campbell, K.J. Ooms,
R.E. Wasylishen, R.R. Tykwinski, Org. Lett. 2005,
7, 3397-3400.
82.
"Synthesis, Structure and Nonlinear Optical Properties of Diarylpolyynes,"
T. Luu, E. Elliott, A.D. Slepkov,
S. Eisler, R. McDonald, F.A. Hegmann, R.R. Tykwinski, Org.
Lett. 2005, 7, 51-54.
81.
"Polyynes as a Model for Carbyne: Synthesis, Physical Properties
and Nonlinear Optical Response," S. Eisler,
A.D. Slepkov, E. Elliott, T. Luu,
R. McDonald, F.A. Hegmann, R.R. Tykwinski, J. Am. Chem. Soc.
2005, 127, 2666-2676.
80.
"Synthesis, Structure, and Nonlinear Optical Properties of Cross-Conjugated
Perphenylated iso-Polydiacetylene," Y. Zhao,
A.D. Slepkov, Clement Osei Akoto,
R. McDonald, F.A. Hegmann, R.R. Tykwinski, Chem. Eur.
J. 2005, 11, 321-329.
79.
"A Simple, One-step Procedure for the Formation of Chiral Metallomacrocycles,"
K. Campbell, C.A. Johnson
II, R. McDonald, M.J. Ferguson,
M.M. Haley, R.R. Tykwinski, Angew. Chem. Int. Ed. 2004,
43, 59675971.
78.
"Band-Like Transport in Pentacene and Functionalized Pentacene
Thin Films Revealed by Sub-Picosecond Transient Photoconductivity
Measurements," O. Ostroverkhova, D.G. Cooke,
S. Shcherbyna, R. Egerton, F.A. Hegmann, R.R. Tykwinski, J. E. Anthony,
Phys. Rev. B 2005, 71, 035204.
77.
"Liquid Phase Deposition of Poly(ethelyne terephthalate) Films,"
R.M. Bryce, H.T. Nguyen, R.R. Tykwinski, R.G. DeCorby, M.R. Freeman,
Y.Y.Tsui, Mat. Res. Soc. Symp. Proc. 2004,
820, O6.6.1-O6.6.6.
76. "Synthesis
of a Pyridinophane with Endo-Annular Donor Sites," K.
Campbell, N.M. Tiemstra, N.S.
Prepas-Strobeck, R. McDonald, M.J. Ferguson, R.R. Tykwinski, Synlett
2004, 182-186.
75. "The
Surprising Nonlinear Optical Properties of Conjugated Polyynes,"
A.D. Slepkov, F.A. Hegmann, S.
Eisler, E. Elliott, R.R. Tykwinski, J.
Chem. Phys. 2004, 120 68076810.
74. Esters
of 2-Iodoxybenzoic Acid: Soluble and Stable Periodinane Oxidizing
Reagents," V.V. Zhdankin, D.N. Litvinov, A.Y. Koposov, T.
Luu, M.J. Ferguson, R. McDonald, R.R. Tykwinski, ChemComm
2003, 106-107 .
73. "Synthesis
of Naturally Occurring Acetylenes via an Alkylidene Carbenoid Rearrangement,"
A.L.K. Shi Shun, R.R. Tykwinski, J. Org.
Chem. 2003, 68, 1339-1347.
72. "Using
ligand exchange reactions to control the coordination environment
of Pt(II) acetylide complexes: applications to conjugated metallacyclynes,"
K. Campbell, R. McDonald, M.J. Ferguson, R.R.
Tykwinski, J. Organomet. Chem. 2003, 683, 379-387.
71. Alkynyl(phenyl)iodonium
Triflates as Precursors to Iridium(III) sigma-Acetylide Complexes,"
D. Bykowski, R. McDonald, R.R. Tykwinski, Arkivoc
2003, part iv, 2129.
70. "Polyamide-imide
polymer thin films for integrated optics", R.M. Bryce, H.T. Nguyen,
P. Nakeeran, T. Clement, C.J. Haugen, R.R. Tykwinski, R.G. DeCorby,
J.N. McMullin, Thin Solid Films 2004, 458, 233-236.
69. "IBX
Amides: A New Family of Hypervalent Iodine Reagents," V.V. Zhdankin,
A.Y. Koposov, B.C. Netzel, Nikolai V. Yashin, M.J. Ferguson, B.P.
Rempel, R.R. Tykwinski, Angew. Chem. Int. Ed., 2003, 42, 2194-2196.
68. Invited
Highlight: "Evolution in the Palladium-Catalyzed Cross-Coupling of sp-
and sp2-hybridized Carbon," R.R. Tykwinski, Angew. Chem.
Int. Ed. 2003, 9, 2542-2550.
67. Synthesis
and Derivatization of Ethynyl alpha,alpha-Dibromomethyl Ketones: Formation
of Highly Functionalized Vinyl Triflates," T.
Rankin, R.R. Tykwinski, Org. Lett., 2003, 5,
213-216.
66. "Alkyne
Migration in Alkylidene Carbenoid Species: A New Method of Polyyne Synthesis," S. Eisler, N.
Chahal, R. McDonald, R.R. Tykwinski, Chem. Eur. J., 2003, 9, 2542-2550.
65. Ammonium
Cyanate Shows NHN Hydrogen Bonding, Not NHO,
E.J. MacLean, K.D.M. Harris, B.M. Kariuki, S.J. Kitchin, R.R. Tykwinski,
I.P. Swainson, J.D. Dunitz, J. Am. Chem. Soc., 2003, 125,
14449-14451.
64. "Synthesis
of Unsymmetrical Substituted 1,3-Butadiynes and 1,3,5-Hexatriynes via
Alkylidene Carbenoid Rearrangements," A.L.K.
Shi Shun, E.T. Chernick, S. Eisler, R.R. Tykwinski, J.
Org. Chem., 2003, 68, 1339-1347.
63. "Functionalized
Macrocyclic Ligands: Big Building Blocks for Metal Coordination," K. Campbell, R. McDonald, M.J. Ferguson,
R.R. Tykwinski, Organometallics, 2003, 22, 1353-1355.
62. "Preparation,
Structure, and Unexpected Chemistry of Phosphoranyl Derived Benziodoxoles,"
V. V. Zhdankin, O. Maydanovych, J. Herschbach, R. McDonald, R. R. Tykwinski, J. Am. Chem. Soc., 2002, 124, 11614-11615.
61. "Picosecond
Transient Photoconductivity in Functionalized Pentacene Molecular Crystals
Probed by Terahertz Pulse Spectroscopy," F.A. Hegmann, R.R. Tykwinski,
K.P.H. Lui, J.E. Bullock, J. E. Anthony, Phys. Rev. Lett., 2002, 89, 227403.
60. "Coordination
Driven Self-Assembly: Solids with Bidirectional Porosity," K.
Campbell, C.J. Kuehl, M.J. Ferguson, P.J. Stang, R.R. Tykwinski, J. Am. Chem. Soc., 2002, 124, 7266-7267.
59. "Optical
Properties of Cross-Conjugated iso-Polydiacetylene Oligomers
as Measured UV-Vis Spectroscopy and the Optical Kerr Effect," A.D.
Slepkov, F.A. Hegmann, K. Kamada, Y.
Zhao, R.R. Tykwinski, J Opt. A, Pure Appl. Op. 2002, 4, S207-S211.
58. "Nonlinear
Optical Properties of Thienyl and Bithienyl Iodonium Salts as Measured
by the Z-scan Technique," R.R. Tykwinski, K. Kamada, D.
Bykowski, F.A. Hegmann, R.J. Hinkle J Opt.
A, Pure Appl. Op. 2002, 4, S202-S206.
57. "Ultrafast
Optical Kerr Effect Measurements of Third-Order Nonlinearities in Cross-Conjugated iso-Polydiacetylene Oligomers," A.D.
Slepkov, F.A. Hegmann, Y. Zhao,
R.R. Tykwinski, K. Kamada, J. Chem. Phys. 2002, 116,
3834-3840.
56. Invited
Account: "Cross-conjugated (Oligo)enynes," R.R. Tykwinski, Y. Zhao, Synlett, 2002,
1939-1953.
55. "Study
of Cross-conjugated iso-Polytriacetylenes and Related Oligoenynes," Y. Zhao, R. McDonald, R.R. Tykwinski, J. Org. Chem. 2002, 67, 2805-2812.
54. "The
effects of p-acceptor and p-donor substitution in cross-conjugated enynes," Y. Zhao, S.C.
Ciulei, R.R. Tykwinski, Tetrahedron Lett. 2001, 42, 7721-7723.
53. "Functionalized
Macrocyclic Ligands for Use in Supramolecular Chemistry," K.
Campbell, R. McDonald, R.R. Tykwinski, J. Org. Chem., 2002, 67, 1133-1140.
52. "Structural
and Electronic Characteristics of Thienyl(aryl)iodonium Triflates," D. Bykowski, R. McDonald, R.J. Hinkle,
R.R. Tykwinski, J. Org. Chem. 2002, 67, 2798-2804.
51. "Modification
of the Fritsch-Buttenberg-Wiechell Rearrangement: A Facile Route to
Unsymmetrical Butadiynes," E.T. Chernick, S. Eisler, R.R. Tykwinski, Tetrahedron
Lett. 2001, 42, 8575-8578.
50. "Iterative
Synthesis and Characterization of Cross-conjugated iso-Polydiacetylenes," Y. Zhao, K.
Campbell, R.R. Tykwinski J. Org. Chem. 2002, 67, 336-344.
49. "Secondary
Bonding-Directed Self-Assembly of Amino Acid Derived Benziodazoles:
Synthesis and Structure of Novel Hypervalent Iodine Macrocycles,"
V.V. Zhdankin, A.E. Koposov, J.T. Smart, R.R. Tykwinski, R. McDonald,
A. Morales-Izquierdo, J. Am. Chem. Soc. 2001, 123, 4095-4096.
48. "Functionalization
of Buckminsterfullerene by Hypervalent Iodine Reagents," V.V. Zhdankin,
K.J. Hanson, A.E. Koposov, E. Blomquist, R.R. Tykwinski, Mendeleev
Commun. 2001, 51-52.
47. "Rigid,
Cross-conjugated Macrocycles: A Cyclic Alternative to 4,4-Bipyridines
in Supramolecular Chemistry," K. Campbell,
R. McDonald, N.R. Branda, R.R. Tykwinski, Org. Lett. 2001, 3, 1045-48.
46. "Migrating
Alkynes in Vinylidene Carbenoids: An Unprecedented Route to Polyynes," S. Eisler, R.R. Tykwinski, J.
Am. Chem. Soc. 2000, 122, 10736-10737.
45. "Cross-conjugated
Chromophores: Synthesis of iso-Polydiacetylenes with Donor/Acceptor
Substitution," S.C. Ciulei,
R.R. Tykwinski, Org. Lett. 2000, 2, 3607-3610.
44. "Structural,
Vibrational, and Electronic Characteristics of Enyne Macrocycles as
a Function of Ring Strain," S. Eisler,
R. McDonald, G.R. Loppnow, R.R. Tykwinski, J. Am. Chem. Soc. 2000, 122, 6917-6928.
43. "Synthesis
and Characterization of Cross-conjugated Polyenynes," Y.
Zhao, R. McDonald, R.R. Tykwinski, Chem. Commun. 2000, 77-78.
42. "Thienyl(phenyl)iodonium
Triflates Structural and Linear and Nonlinear Optical Behavior
of Hypervalent Iodine Derivatives," R.R. Tykwinski, K. Kamada, D. Bykowski, K. Ohta, R. McDonald, Adv. Mater. 2000, 12, 133-137.
41. "Expanded
Radialenes: Modular Synthesis and Characterization of Cross-conjugated
Enyne Macrocycles," S. Eisler,
R.R. Tykwinski, Angew. Chem. Int. Ed. 1999, 38, 1940-1943.
40. "Cyclic
Alkynes Electronic Behavior as a Function of Ring Strain,"
R.R. Tykwinski, Chem. Commun. 1999, 905-906.
39. "Iterative
Synthesis and Properties of Cross-conjugated iso-Polydiacetylene
Oligomers," Y. Zhao, R.R. Tykwinski, J. Am. Chem. Soc. 1999, 121, 458-459.
38. "New
Light on an Old Story: The Solid-State Transformation of Ammonium Cyanate
into Urea," J.D. Dunitz, K.D.M. Harris, R.L. Johnston, B.M. Kariuki,
E.J. MacLean, K. Psallidas, W.B. Schweizer, R.R. Tykwinski, J. Am.
Chem. Soc. 1998, 120, 13274-13275.
Post-doctoral
work
37. "Highly
Functionalized Dimeric Tetraethynylethenes and Expanded Radialenes:
Strong Evidence for Macrocyclic Cross-Conjugation," M.B. Nielsen,
M. Schreiber, Y.G. Baek, P. Seiler, S. Lecomte, C. Boudon, R.R. Tykwinski,
J.-P. Gisselbrecht, V. Gramlich, P.J. Skinner, C. Bosshard, P. Günter,
M. Gross, F. Diederich, Chem. Eur. J. 2001, 7,
3263-3280.
36. "Donor/Acceptor-Tetraethynylethenes
with Nitrothienyl Substituents: Structure-Property Relationships,"
R.R. Tykwinski, A. Hilger, F. Diederich, H.P. Lüthi, P. Seiler,
V. Gramlich, J.-P. Gisselbrecht, C. Boudon, M. Gross, Helv. Chim.
Acta 2000, 83, 1484-1508.
35. "Functionalized
Two-dimensionally Conjugated Molecules for Third-order Nonlinear Optics,"
U. Gubler, R. Martin, R. Spreiter, R.R. Tykwinski, C. Bosshard, P. Gunter,
F. Diederich, Mol Cryst. Liq. Cryst. Sect. B 1999, 22, 323-328.
34. "Functionalized
One- and Two-Dimensionally Conjugated Molecules for Third-Order Nonlinear
Optics," U. Gubler, R. Spreiter, Ch. Bosshard, P. Günter,
R.R. Tykwinski, F. Diederich, Polym. Prepr. 1998, 39,
1067-1068.
33. "Porphyrin-[(E)-1,2-Diethynylethene]
Scaffolding: Synthesis and Optical and Electrochemical Properties of
Multinanometer-Sized Porphyrin Arrays," J. Wytko, V. Berl, M. McLaughlin,
R.R. Tykwinski, M. Schreiber, F. Diederich, C. Boudon, J.-P. Gisselbrecht,
M. Gross, Helv. Chim. Acta 1998, 81, 1964-1977.
32. "Two-Dimensionally
Conjugated Molecules: The Importance of Low Molecular Symmetry for Large
Third-Order Nonlinear Optical Effects," U. Gubler, R. Spreiter,
Ch. Bosshard, P. Günter, R.R. Tykwinski, F. Diederich, Appl.
Phys. Lett. 1998, 73, 2396-2398.
31. "Synthesis
of a Highly Strained Permethylenated Cycloocta-1,5-diyne Derivative
by Acid-Catalysed Thermal Rearrangement," S. Kammermeier, R.R.
Tykwinski, P. Siemsen, P. Seiler, F. Diederich, Chem. Commun. 1998, 37, 1285-1286.
30. "Structure-Property
Relationships in Third-Order Nonlinear Optical Chromophores," R.R.
Tykwinski, U. Gubler, R. E. Martin, F. Diederich, Ch. Bosshard, P. Günter, J. Phys. Chem. B 1998, 102, 4451-4465.
29. "Photochemical trans-cis isomerisation of donor/acceptor-substituted
(E)-hex-3-ene-1,5-diynes (1,2-diethynylethenes, DEEs) and 3,4-diethynylhex-3-ene-1,5-diynes
(tetraethynylethenes, TEEs)," R.E. Martin, J. Bartek, F. Diederich,
R.R. Tykwinski, E. Meister, A. Hilger, H.P. Lüthi, J. Chem.
Soc., Perkin 2 1998, 233-241.
28. "One-
and Two-Dimensionally Conjugated Tetraethynylethenes: Structure versus
Second-Order Optical Properties," R. Spreiter, Ch. Bosshard, G.
Knöpfle, P. Günter, R.R. Tykwinski, M. Schreiber, F. Diederich, J. Phys. Chem. B 1998, 102, 29-32.
27. "Tetraethynylethene
Molecular Scaffolding," R.R. Tykwinski, F. Diederich, Liebigs
Ann. 1997, 649-661.
26. "Electronic
Characteristics of Arylated Tetraethynylethenes: A Cooperative Computational
and Electrochemical Investigation," A. Hilger, J.-P. Gisselbrecht,
R.R. Tykwinski, C. Boudon, M. Schreiber, R.E. Martin, H.P. Lüthi,
M. Gross, F. Diederich, J. Am. Chem. Soc. 1997, 119,
2069-2078.
25. "Tetraethynylethene
Molecular Scaffolding: Nonlinear Optical, Redox, and Amphiphilic Properties
of Donor Functionalized Polytriacetylene and Expanded Radialenes,"
M. Schreiber, R.R. Tykwinski, F. Diederich, R. Spreiter, U. Gubler,
Ch. Bosshard, I. Poberaj, P. Günter, C. Boudon, J.-P. Gisselbrecht,
M. Gross, U. Jonas, H. Ringsdorf, Adv. Mater. 1997, 9,
339-343.
24. "Methanofullerene
Molecular Scaffolding: Towards C60-Substituted Poly(triacetylene)s and
Expanded Radialenes, Preparation of a C60-C70 Hybrid Derivative, and a Novel Macrocyclization Reaction," J.-F.
Nierengarten, A. Herrmann, R.R. Tykwinski, M. Rüttimann, F. Diederich,
C. Boudon, J.-P. Gisselbrecht, M. Gross, Helv. Chim. Acta 1997, 80, 293-316.
23. "Donor-Acceptor-Substituted
Tetraethynylethenes: Systematic Assembly of Molecules for Use as Advanced
Materials," R.R. Tykwinski, M. Schreiber, R. Pérez Carlón,
F. Diederich, V. Gramlich, Helv. Chim. Acta 1996, 79, 2249-2281.
22. "1,1,2,2-Tetraethynylethanes:
Synthons for Tetraethynylethenes and Modules for Acetylenic Molecular
Scaffolding," R.R. Tykwinski, F. Diederich, V. Gramlich, P. Seiler, Helv. Chim. Acta 1996, 79, 634-645.
21. "Towards
the Synthesis of Tetraethynylallene," T. Lange, J.-D. van Loon,
R.R. Tykwinski, M. Schreiber, F. Diederich, Synthesis 1996,
537-550.
20. "Structure-Property
Relationships in Nonlinear Optical Tetraethynylethenes," Ch. Bosshard,
R. Spreiter, P. Günter, R.R. Tykwinski, M. Schreiber, F. Diederich, Adv. Mater. 1996, 8, 231-234.
19. "Donor-Acceptor
Substituted Tetraethynylethenes," R.R. Tykwinski, M. Schreiber,
V. Gramlich, P. Seiler, F. Diederich, Adv. Mater. 1996, 8, 226-231.
18. "Preparation
of Conjugated Rigid-Rod, Di- and Trimetallic, s-Acetylide Complexes
of Iridium(III) and Rhodium(III) via Alkynyl(phenyl)iodonium Chemistry,"
R.R. Tykwinski, P.J. Stang, Organometallics 1994, 13,
3203-3208.
17. "A
New Method for the Synthesis of Cyclopentenones via the Tandem Michael
Addition-Carbene Insertion Reaction of b-Ketoethynyl(phenyl)iodonium
Salts," B.L. Williamson, R.R. Tykwinski, P.J. Stang, J. Am.
Chem. Soc. 1994, 116, 93-98.
16. "Preparation
of Bis-Cyclopentene Ring Systems Via Reaction of Bis[phenyl(iodonium)]
Diyne Triflates with Soft Nucleophiles," R.R. Tykwinski, P.J. Stang,
N.E. Persky, Tetrahedron Lett. 1994, 35, 23-26.
15. "Highly
Effective PQQ Inhibition by Alkynyl and Aryl Mono- and Diiodonium Salts,"
P.M. Gallop, M.A. Paz, R. Flückiger, P.J. Stang, V.V. Zhdankin,
R.R. Tykwinski, J. Am. Chem. Soc. 1993, 115, 11702-11704.
Graduate
and undergraduate work
14. "A
New Synthesis of Alkynyl Sulfones and Single Crystal X-Ray Structure
of p-(Tolyl-sulfonyl)ethyne," R.R. Tykwinski, B.L. Williamson,
D.R. Fischer, P.J. Stang, A.A. Arif, J. Org. Chem. 1993, 58, 5235-5237.
13. "Functionalization
of Diynes. Preparation of Bis(alkynyl) Ditosylate and Dibenzoate Esters
and Bis(alkynyl) Dithiocyanates Via Alkynyl Iodonium Chemistry,"
R.R. Tykwinski, P.J. Stang, Tetrahedron 1993, 49,
3043-3052.
12. "Alkylidenecarbene
Insertions into Aromatic C-H Bonds in Solution," R.R. Tykwinski,
J.A. Whiteford, P.J. Stang, J. Chem. Soc., Chem. Comm. 1993,
1800-1801.
11. "(Dicyano)iodonium
Triflate Novel Iodonium Species and a Versatile Reagent for the
Preparation of Iodonium Salts Via an Iodonium Transfer Reaction with
Organostannanes," P.J. Stang, V.V. Zhdankin, R.R. Tykwinski, N.S.
Zefirov, Tetrahedron Lett. 1992, 33, 1419.
10. "Preparation
of bis-(Heteroaryl)iodonium Salts Via an Iodonium Transfer Reaction
Between Di(cyano)iodonium Triflate and Organostannanes," P.J. Stang,
R.R. Tykwinski, V.V. Zhdankin, J. Heterocyclic Chem. 1992, 29, 815-818.
9. "Single
Step Preparation of Rigid-Rod, Cationic, Bimetallic, s-Diyne Complexes:
L5M+CºC-(C6H4)-CºCM+L5 2TfO, M = Ir, Rh," P.J. Stang,
R.R. Tykwinski, J. Am. Chem. Soc. 1992, 114, 4411-4412.
8. "Bis[(phenyl)iodonium]
Diyne Triflates PhICºC-(pC6H4)n-CºCIPh 2OTf and PhICºC-(CH2)n-CºCIPh
2OTf: Preparation, Characterization, and Reaction with Triphenyl Phosphine,"
P.J. Stang, R.R. Tykwinski, V.V. Zhdankin, J. Org. Chem. 1992, 57, 1861-1864.
7. "Iodosyl
Trifluoromethane Sulfonate- An Efficient Reagent for the Single Step
Preparation of Diaryliodonium Triflate Salts," P.J. Stang, V.V.
Zhdankin, R.R. Tykwinski, N.S. Zefirov, Tetrahedron Lett. 1991, 32, 7497-7498.
6. "(Dicyanoiodo)Benzene-
A Stable Tricoordinate Iodine(III) Compound with Three Carbon Ligands,"
V.V. Zhdankin, R.R. Tykwinski, B.L. Williamson, P.J. Stang, N.S. Zefirov, Tetrahedron Lett. 1991, 32, 733-734.
5. "Iodosobenzene
Tetrafluoroborate, Hexafluoroantimonate, and Hexafluorophosphate: Stable
Electrophilic Hypervalent Iodine Reagent Without Nucleophilic Ligands,"
V.V. Zhdankin, R.R. Tykwinski, B. Berglund, M. Mullikin, R. Caple, N.S.
Zefirov, A.S. Koz'min, J. Org. Chem. 1989, 54, 2609-2612.
4. "Carbon-Carbon
Bond Formation in Reactions of PhIO HBF4/Silyl Enol Ether Adduct with
Alkenes or Silyl Enol Ethers," V.V. Zhdankin, M. Mullikin, R.R.
Tykwinski, B. Berglund, R. Caple, N.S. Zefirov, A.S. Koz'min, J.
Org. Chem. 1989, 54, 2605-2608.
3. "Ring
Contraction of Cyclic Olefins with Iodine(III) Containing Reagents,"
N.S. Zefirov, R. Caple, B. Berglund, V.A. Palyulin, R.R. Tykwinski,
V.V. Zhdankin, A.S. Koz'min, Izv. AN SSSR Ser. Khim. 1988,
1452-1454.
2. "Iodosobenzene
Tetrafluoroborate: First Example of a Stable Electrophilic Hypervalent
Iodine Reagent Without Nucleophilic Ligands," V.V. Zhdankin, R.R.
Tykwinski, R. Caple, B. Berglund, A.S. Koz'min, N.S. Zefirov, Tetrahedron
Lett. 1988, 29, 3717-3720.
1. "Reaction
of PhIO HBF4/Silyl Enol Ether Adduct with Olefins as a General Approach
to Carbon-Carbon Bond Formation in AdE Reactions Using Hypervalent Iodine
Reagents," V.V. Zhdankin, R.R. Tykwinski, R. Caple, B. Berglund,
A.S. Koz'min, N.S. Zefirov, Tetrahedron Lett. 1988, 29,
3703-3704.
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