 |
CHEM 102/105 Section H1 Problem Sets |
|
Home Teaching philosophy Course details Lab notices Lecture notes (PDF) Lecture notes (HTML) Interactive demos Formula sheet Glossary Hand-outs Midterm central Chemistry Department University of Alberta Periodic Table of the Elements Contact me |
For the most part, problems will be assigned from the textbook (Zumdahl Chemistry, 5th edition). Problem sets will not be graded, but you are strongly encouraged to do them. Worked solutions will be posted on the notice board outside W3-60 and on this website.
Problem Set 15.49, 5.53, 5.57, 5.61, 5.65, 5.71, 5.93(a-c), 5.93(d-f), 5.95 (Gases, the ideal gas law, units of pressure, temperature and volume and unit conversions, Dalton's law of partial pressures, kinetic molecular theory)Problem Set 25.73, 5.79, 5.85, 8.25, 8.85(a,b), 8.85(c,d), 8.89, 10.35, 10.43 (Real gases and the van der Waals equation, intermolecular forces, dipole moments, electronegativities, London dispersion forces)Problem Set 310.47, 10.49, 10.49(contd.), 10.63(a), 10.63(b)-(d), 10.73, 10.87, 10.87(contd.), 10.89, 10.89(contd.), 10.91 (Solids, solid classifications, lattices, asymmetric units, unit cells, simple, body-centred and face-centred cubic cells, metals, hexagonal closest packing, cubic closest packing, ionic solids, Bragg's law)Problem Set 415.81, 15.83, 15.91, 15.93, 15.99, 15.105, 15.109, 15.111 (Solubility, solubility product, complex ion equilibria)Problem Set 5a6.27, 6.31, 6.33, 6.37, 6.47 (Thermodynamics (contrasted with kinetics), energy (kinetic and potential), first law of thermodynamics, system and surroundings, state functions, internal energy, enthalpy, calorimetry)Related notes: [PDF Lecture 9]
Problem Set 5b6.55, 6.61, 6.89, 6.93 (Calorimetry, Hess's Law, standard states, standard enthalpies of formation, heats of reaction, bond dissociation energies)Related notes: [PDF Lecture 10]
Problem Set 66.17, 6.21, 6.23, 6.37, 6.43, 6.45, 6.53, 6.71 (Spontaneity, entropy and free energy, entropy changes with temperature, phase changes, dissolution and molecular size and complexity, entropy of reaction, free energy of reaction)Related notes: [PDF Lecture 11] [PDF Lecture 12]
Problem Set 716.33, 16.37, 16.43, 16.45, 16.55, 16.65, 16.71, 16.73, 16.85 (Spontaneity, entropy and free energy, entropy changes with temperature, phase changes, dissolution and molecular size and complexity, entropy of reaction, free energy of reaction)Related notes: [PDF Lecture 13]
Problem Set 817.29, 17.31, 17.33, 17.37, 17.45, 17.51 (Introduction to oxidation and reduction, balancing redox reactions, galvanic cells, line notation, electromotive force, standard hydrogen electrode, cell potential, relationship to free energy)Related notes: [PDF Lecture 14]
Problem Set 917.55, 17.61, 17.69, 17.73, 17.79, 17.83, 17.89, 17.101, 17.105Related notes: [PDF Lecture 15] [PDF Lecture 16]
Problem Set 1012.21, 12.25, 12.27, 12.31, 12.35, 12.39, 12.43, 12.53, 12.59, 12.73 (Kinetics contrasted with thermodynamics, the differential rate law and methods for determination, method of initial rates, the integrated rate law derived for 1st and 2nd order reactions, half lives, integrated rate law for zero-order reactions, pseudo-first-order conditions and rate constant, general method for rate-law determinations, reaction mechanisms, elementary steps, molecularity, rate-determining step, collision model, Arrhenius equation, catalysts)Problem Set 1120.21, 20.23, 20.25, 20.31, 20.33, 20.35, 20.37, 20.39, 20.41, 20.43, 20.45 (Transition metal complexes, Werner's experiments, ligands, isomers, nomenclature)Related notes: [PDF Lecture 21] [PDF Lecture 22]
|
