Detection of Rotational Spectra of He-Containing van der Waals Complexes with a Fourier Transform Microwave Spectrometer.
Yunjie Xu and Wolfgang Jäger
Department of Chemistry, University of Alberta, Edmonton AB T6G 2G2, Canada
The recent report of the rotational spectrum of He–OCS by Higgins and Klemperer encouraged us to search for transitions of He-containing van der Waals complexes with our pulsed molecular beam Fourier transform microwave spectrometer. It was possible to measure additional transitions of the normal isotopomer and the previously unobserved spectra of several rarer isotopomers of He–OCS, including He–OC34S, He-O13CS, and He–OC33S. 33S nuclear quadrupole hyperfine structure could be resolved and analyzed in case of He–OC33S. Spectra of two further He-molecule complexes, i.e. He–CO and He–CO2, will also be presented. For He–CO, transitions of the rarer isotopomers He-C18O, He–>sup>13CO, He–>sup>13C18O, and He–>sup>13C17O were also measured. In the case of He–CO2 it was possible to detect transitions of three more istotopomers, i.e. He–>sup>13CO2, He–>sup>18O13CO, and He–>sup>17OCO. For both 17O containing complexes, the 17O nuclear quadrupole hyperfine structures were detected and analyzed.