The vibrationally mediated photodissociation of Cl2

S. M. Ibrahim Al-Rafia, Mohammad R. Momeni, Robert McDonald, Michael J. Ferguson, Alex Brown and Eric Rivard

Department of Chemistry, University of Alberta 11227 Saskatchewan Dr., Edmonton, Alberta, T6G 2G2 Canada


Abstract

To branch or not to branch: A mild stepwise route to various linear and branched (GeCl2)x oligogermylenes supported by Lewis bases is reported, including the carbene-bound Ge4 complex NHC·GeCl2Ge(GeCl3)2 (see picture). Dipp = 2,6-iPr2C6H3, NHC = N-hetero-cyclic carbene.


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Last updated August 13, 2013.